- Sand Gravel & Aggregate, Valley City
- Sandwich Shop Restaurants, Valley City
- Satellite TV Service, Valley City
- Savings Banks, Valley City
- Screen Printing, Valley City
- Secondary Schools, Valley City
- Security & Surveillance System & Equipment, Valley City
- Security Alarm Systems - Home & Business, Valley City
- Security Brokers & Dealers, Valley City
- Security Control Systems & Monitoring, Valley City - Polygraph, Lie Detector, CCTV, Fire Sensor Equipment, Etc
- Security Services, Valley City
- Seed & Grain Cleaning, Valley City
- Seeds & Bulbs Wholesale & Growers, Valley City
- Senior Citizens Information & Services, Valley City
- Senior Citizens Service & Health Organizations, Valley City
- Sewer & Drain Cleaning & Repair, Valley City - Drain Cleaner & Installation Services
- Sheet Metal, Valley City
- Shoe Dyers, Valley City
- Shoe Repair & Shoeshine Parlors, Valley City
- Shoe Repair Shops, Valley City
- Shoe Stores, Valley City - Mens, Womens & Kids Shoes
- Shopping & Shopping Services, Valley City
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- Siding Contractors, Valley City - Vinyl Siding, Wood, Metal & Aluminum Siding Contractors - Installation & Repair
- Signs, Valley City
- Smoking Cessation Treatment Centers & Information Services, Valley City
- Snowmobile Dealers, Valley City - Parts, Gear, Clothing & Accessories
- Social Services & Welfare, Valley City
- Societies & Foundation Associations, Valley City
- Special Education & Care, Valley City
- Special Interest Schools Or Instruction, Valley City
- Specialty Communication Companies & Services, Valley City
- Specialty Stores, Valley City
- Speech & Hearing Specialists, Valley City
- Staffing & Support Services, Valley City
- State Government, Valley City
- Steel & Metal Goods, Valley City - Steel Distributors
- Stock & Bond Brokers & Dealers, Valley City
- Stocks & Bond Brokers, Valley City
- Stoves & Furnace Equipment, Valley City - Fittings & Repair Parts
- Submarine Sandwich Restaurants, Valley City
- Substance Abuse Outpatient Clinics, Valley City
- Supper Club Restaurants, Valley City
- Surveyor Services, Valley City - Surveying Service
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